Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient Solution

STEP 0: Pre-Calculation Summary
Formula Used
Acentric Factor = (Reduced Second Virial Coefficient-Pitzer Correlations Coefficient B(0))/Pitzer Correlations Coefficient B(1)
ω = (B^-B0)/B1
This formula uses 4 Variables
Variables Used
Acentric Factor - Acentric Factor is a standard for the phase characterization of single & pure components.
Reduced Second Virial Coefficient - The Reduced Second Virial Coefficient is the function of the second virial coefficient, critical temperature and critical pressure of the fluid.
Pitzer Correlations Coefficient B(0) - Pitzer Correlations Coefficient B(0) is calculated from Abott equation. It's a function of reduced temperature.
Pitzer Correlations Coefficient B(1) - Pitzer Correlations Coefficient B(1) is calculated from Abott equation. It's a function of reduced temperature.
STEP 1: Convert Input(s) to Base Unit
Reduced Second Virial Coefficient: 0.29 --> No Conversion Required
Pitzer Correlations Coefficient B(0): 0.2 --> No Conversion Required
Pitzer Correlations Coefficient B(1): 0.25 --> No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
ω = (B^-B0)/B1 --> (0.29-0.2)/0.25
Evaluating ... ...
ω = 0.36
STEP 3: Convert Result to Output's Unit
0.36 --> No Conversion Required
FINAL ANSWER
0.36 <-- Acentric Factor
(Calculation completed in 00.004 seconds)

Credits

Created by Shivam Sinha
National Institute Of Technology (NIT), Surathkal
Shivam Sinha has created this Calculator and 300+ more calculators!
Verified by Akshada Kulkarni
National Institute of Information Technology (NIIT), Neemrana
Akshada Kulkarni has verified this Calculator and 900+ more calculators!

21 Equation of States Calculators

Compressibility Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient
Go Compressibility Factor = 1+((Pitzer Correlations Coefficient B(0)*Reduced Pressure)/Reduced Temperature)+((Acentric Factor*Pitzer Correlations Coefficient B(1)*Reduced Pressure)/Reduced Temperature)
B(0) given Z(0) using Pitzer Correlations for Second Virial Coefficient
Go Pitzer Correlations Coefficient B(0) = modulus(((Pitzer Correlations Coefficient Z(0)-1)*Reduced Temperature)/Reduced Pressure)
Reduced Second Virial Coefficient using Second Virial Coefficient
Go Reduced Second Virial Coefficient = (Second Virial Coefficient*Critical Pressure)/([R]*Critical Temperature)
Second Virial Coefficient using Reduced Second Virial Coefficient
Go Second Virial Coefficient = (Reduced Second Virial Coefficient*[R]*Critical Temperature)/Critical Pressure
Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient
Go Acentric Factor = (Reduced Second Virial Coefficient-Pitzer Correlations Coefficient B(0))/Pitzer Correlations Coefficient B(1)
Reduced Second Virial Coefficient using B(0) and B(1)
Go Reduced Second Virial Coefficient = Pitzer Correlations Coefficient B(0)+Acentric Factor*Pitzer Correlations Coefficient B(1)
Z(0) given B(0) using Pitzer Correlations for Second Virial Coefficient
Go Pitzer Correlations Coefficient Z(0) = 1+((Pitzer Correlations Coefficient B(0)*Reduced Pressure)/Reduced Temperature)
Acentric Factor using Pitzer Correlations for Compressibility Factor
Go Acentric Factor = (Compressibility Factor-Pitzer Correlations Coefficient Z(0))/Pitzer Correlations Coefficient Z(1)
Compressibility Factor using Second Virial Coefficient
Go Compressibility Factor = 1+((Second Virial Coefficient*Pressure)/([R]*Temperature))
Compressibility Factor using Pitzer Correlations for Compressibility Factor
Go Compressibility Factor = Pitzer Correlations Coefficient Z(0)+Acentric Factor*Pitzer Correlations Coefficient Z(1)
Z(1) given B(1) using Pitzer Correlations for Second Virial Coefficient
Go Pitzer Correlations Coefficient Z(1) = (Pitzer Correlations Coefficient B(1)*Reduced Pressure)/Reduced Temperature
B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient
Go Pitzer Correlations Coefficient B(1) = (Pitzer Correlations Coefficient Z(1)*Reduced Temperature)/Reduced Pressure
Second Virial Coefficient using Compressibility Factor
Go Second Virial Coefficient = ((Compressibility Factor-1)*[R]*Temperature)/Pressure
Compressibility Factor using Reduced Second Virial Coefficient
Go Compressibility Factor = 1+((Reduced Second Virial Coefficient*Reduced Pressure)/Reduced Temperature)
Reduced Second Virial Coefficient using Compressibility Factor
Go Reduced Second Virial Coefficient = ((Compressibility Factor-1)*Reduced Temperature)/Reduced Pressure
Saturated Reduced Pressure at Reduced Temperature 0.7 using Acentric Factor
Go Saturated Reduced Pressure at Reduced Temp 0.7 = exp(-1-Acentric Factor)
Acentric Factor using Saturated Reduced Pressure given at Reduced Temperature 0.7
Go Acentric Factor = -1-ln(Saturated Reduced Pressure at Reduced Temp 0.7)
Reduced Temperature
Go Reduced Temperature = Temperature/Critical Temperature
B(0) using Abbott Equations
Go Pitzer Correlations Coefficient B(0) = 0.083-0.422/(Reduced Temperature^1.6)
B(1) using Abbott Equations
Go Pitzer Correlations Coefficient B(1) = 0.139-0.172/(Reduced Temperature^4.2)
Reduced Pressure
Go Reduced Pressure = Pressure/Critical Pressure

Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient Formula

Acentric Factor = (Reduced Second Virial Coefficient-Pitzer Correlations Coefficient B(0))/Pitzer Correlations Coefficient B(1)
ω = (B^-B0)/B1

Why we use Virial Equation of State?

Since the perfect gas law is an imperfect description of a real gas, we can combine the perfect gas law and the compressibility factors of real gases to develop an equation to describe the isotherms of a real gas. This Equation is known as the Virial Equation of state, which expresses the deviation from ideality in terms of a power series in the density.
The actual behavior of fluids is often described with the virial equation:
PV = RT[1 + (B/V) + (C/(V^2)) + ...] ,
where,
B is the second virial coefficient,
C is called the third virial coefficient, etc.

in which the temperature-dependent constants for each gas are known as the virial coefficients. The second virial coefficient, B, has units of volume (L).

Why we modify the second virial coefficient to reduced second virial coefficient?

Since the tabular nature of the generalized compressibility-factor correlation is a disadvantage, but the complexity of the functions Z(0) and Z(1) precludes their accurate representation by simple equations. Nonetheless, we can give approximate analytical expression to these functions for a limited range of pressures. So we modify the second virial coefficient to reduced the second virial coefficient.

How to Calculate Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient?

Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient calculator uses Acentric Factor = (Reduced Second Virial Coefficient-Pitzer Correlations Coefficient B(0))/Pitzer Correlations Coefficient B(1) to calculate the Acentric Factor, The Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient formula is defined as the ratio of the difference of reduced second virial coefficient and B(0) to the B(1), where B(0) and B(1) are functions of reduced temperature only. Acentric Factor is denoted by ω symbol.

How to calculate Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient using this online calculator? To use this online calculator for Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient, enter Reduced Second Virial Coefficient (B^), Pitzer Correlations Coefficient B(0) (B0) & Pitzer Correlations Coefficient B(1) (B1) and hit the calculate button. Here is how the Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient calculation can be explained with given input values -> 0.36 = (0.29-0.2)/0.25.

FAQ

What is Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient?
The Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient formula is defined as the ratio of the difference of reduced second virial coefficient and B(0) to the B(1), where B(0) and B(1) are functions of reduced temperature only and is represented as ω = (B^-B0)/B1 or Acentric Factor = (Reduced Second Virial Coefficient-Pitzer Correlations Coefficient B(0))/Pitzer Correlations Coefficient B(1). The Reduced Second Virial Coefficient is the function of the second virial coefficient, critical temperature and critical pressure of the fluid, Pitzer Correlations Coefficient B(0) is calculated from Abott equation. It's a function of reduced temperature & Pitzer Correlations Coefficient B(1) is calculated from Abott equation. It's a function of reduced temperature.
How to calculate Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient?
The Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient formula is defined as the ratio of the difference of reduced second virial coefficient and B(0) to the B(1), where B(0) and B(1) are functions of reduced temperature only is calculated using Acentric Factor = (Reduced Second Virial Coefficient-Pitzer Correlations Coefficient B(0))/Pitzer Correlations Coefficient B(1). To calculate Acentric Factor using B(0) and B(1) of Pitzer Correlations for Second Virial Coefficient, you need Reduced Second Virial Coefficient (B^), Pitzer Correlations Coefficient B(0) (B0) & Pitzer Correlations Coefficient B(1) (B1). With our tool, you need to enter the respective value for Reduced Second Virial Coefficient, Pitzer Correlations Coefficient B(0) & Pitzer Correlations Coefficient B(1) and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Acentric Factor?
In this formula, Acentric Factor uses Reduced Second Virial Coefficient, Pitzer Correlations Coefficient B(0) & Pitzer Correlations Coefficient B(1). We can use 2 other way(s) to calculate the same, which is/are as follows -
  • Acentric Factor = (Compressibility Factor-Pitzer Correlations Coefficient Z(0))/Pitzer Correlations Coefficient Z(1)
  • Acentric Factor = -1-ln(Saturated Reduced Pressure at Reduced Temp 0.7)
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