Crystal Field Activation Energy for Dissociative Reaction Solution

STEP 0: Pre-Calculation Summary
Formula Used
CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate
CFAEDS = CFSEOh-CFSESqPy
This formula uses 3 Variables
Variables Used
CFAE Dissociative Substitution - (Measured in Diopter) - CFAE Dissociative Substitution is the difference of crystal field stabilization energy of intermediate and reactant .
Crystal Field Splitting Energy Octahedral - (Measured in Diopter) - Crystal Field Splitting Energy Octahedral is the energy separation between the T2g and Eg orbital.
CFSE For Square Pyramidal Intermediate - (Measured in Diopter) - CFSE For Square Pyramidal Intermediate is the extra stability gained due to splitting in square pyramidal complexes.
STEP 1: Convert Input(s) to Base Unit
Crystal Field Splitting Energy Octahedral: 9000 Diopter --> 9000 Diopter No Conversion Required
CFSE For Square Pyramidal Intermediate: 6500 Diopter --> 6500 Diopter No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
CFAEDS = CFSEOh-CFSESqPy --> 9000-6500
Evaluating ... ...
CFAEDS = 2500
STEP 3: Convert Result to Output's Unit
2500 Diopter --> No Conversion Required
FINAL ANSWER
2500 Diopter <-- CFAE Dissociative Substitution
(Calculation completed in 00.004 seconds)

Credits

Created by Torsha_Paul
University of Calcutta (CU), Kolkata
Torsha_Paul has created this Calculator and 200+ more calculators!
Verified by Soupayan banerjee
National University of Judicial Science (NUJS), Kolkata
Soupayan banerjee has verified this Calculator and 800+ more calculators!

12 Stabilization Energy Calculators

Equilibrium Constant for Coordinate Complexes
Go Formation Constant for Coordinate Complexes = (Concentration of Complex Ion^Stoichiometric Coefficient of Complex Ion)/((Concentration of Metal in Complex^Stoichiometric Coefficient of Metal)*(Concentration of Lewis Bases^Stoichiometric Coefficient of Lewis Base))
Transition Energy from T1g to T1gP
Go Transition Energy from T1g to T1gP = (3/5*Energy Difference)+(15*Racah Parameter)+(2*Configuration Interaction)
Transition Energy from A2g to T1gP
Go Transition Energy from A2g to T1gP = (6/5*Energy Difference)+(15*Racah Parameter)+Configuration Interaction
Octahedral Site Stabilization Energy
Go Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral
Crystal Field Splitting Energy for Tetrahedral Complexes
Go Crystal Field Splitting Energy Tetrahedral = ((Electrons In Eg Orbitals*(-0.6))+(0.4*Electrons In T2g Orbital))*(4/9)
Crystal Field Activation Energy for Dissociative Reaction
Go CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate
Crystal Field Splitting Energy for Octahedral Complexes
Go Crystal Field Splitting Energy Octahedral = (Electrons In Eg Orbitals*0.6)+(-0.4*Electrons In T2g Orbital)
Solubility Product of Coordinate Complex
Go Solubility Product of Coordinate Complex = Formation Constant for Coordinate Complexes*Solubility Product
Crystal Field Activation Energy for Associative Reaction
Go CFAE Associative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Pentagonal Bipyramidal
Transition Energy from A2g to T1gF
Go Transition Energy from A2g to T1gF = (9/5*Energy Difference)-Configuration Interaction
Transition Energy from T1g to T2g
Go Transition Energy from T1g to T2g = (4/5*Energy Difference)+Configuration Interaction
Transition Energy from T1g to A2g
Go Transition Energy from T1g to A2g = (9/5*Energy Difference)+Configuration Interaction

Crystal Field Activation Energy for Dissociative Reaction Formula

CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate
CFAEDS = CFSEOh-CFSESqPy

What is Dissociative Mechanism?

A dissociative mechanism or dissociative substitution is a type of organic chemical reaction in which the ligands interchange between molecules, releasing a ligand from the coordination sphere.

What is Dissociative Substitution Reaction ?

Dissociative substitution describes a pathway by which compounds interchange ligands. The term is typically applied to coordination and organometallic complexes, but resembles the Sn1 mechanism in organic chemistry.

How to Calculate Crystal Field Activation Energy for Dissociative Reaction?

Crystal Field Activation Energy for Dissociative Reaction calculator uses CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate to calculate the CFAE Dissociative Substitution, The Crystal Field Activation Energy for Dissociative Reaction formula is defined as the difference of crystal field stabilization energy of intermediate and reactant. CFAE Dissociative Substitution is denoted by CFAEDS symbol.

How to calculate Crystal Field Activation Energy for Dissociative Reaction using this online calculator? To use this online calculator for Crystal Field Activation Energy for Dissociative Reaction, enter Crystal Field Splitting Energy Octahedral (CFSEOh) & CFSE For Square Pyramidal Intermediate (CFSESqPy) and hit the calculate button. Here is how the Crystal Field Activation Energy for Dissociative Reaction calculation can be explained with given input values -> 2500 = 9000-6500.

FAQ

What is Crystal Field Activation Energy for Dissociative Reaction?
The Crystal Field Activation Energy for Dissociative Reaction formula is defined as the difference of crystal field stabilization energy of intermediate and reactant and is represented as CFAEDS = CFSEOh-CFSESqPy or CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate. Crystal Field Splitting Energy Octahedral is the energy separation between the T2g and Eg orbital & CFSE For Square Pyramidal Intermediate is the extra stability gained due to splitting in square pyramidal complexes.
How to calculate Crystal Field Activation Energy for Dissociative Reaction?
The Crystal Field Activation Energy for Dissociative Reaction formula is defined as the difference of crystal field stabilization energy of intermediate and reactant is calculated using CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate. To calculate Crystal Field Activation Energy for Dissociative Reaction, you need Crystal Field Splitting Energy Octahedral (CFSEOh) & CFSE For Square Pyramidal Intermediate (CFSESqPy). With our tool, you need to enter the respective value for Crystal Field Splitting Energy Octahedral & CFSE For Square Pyramidal Intermediate and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
Let Others Know
Facebook
Twitter
Reddit
LinkedIn
Email
WhatsApp
Copied!