Octahedral Site Stabilization Energy Solution

STEP 0: Pre-Calculation Summary
Formula Used
Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral
OSSE = CFSEOh-CFSETd
This formula uses 3 Variables
Variables Used
Octahedral Site Stabilization Energy - (Measured in Diopter) - Octahedral Site Stabilization Energy is the difference between the CFSE values in octahedral and tetrahedral geometries.
Crystal Field Splitting Energy Octahedral - (Measured in Diopter) - Crystal Field Splitting Energy Octahedral is the energy separation between the T2g and Eg orbital.
Crystal Field Splitting Energy Tetrahedral - (Measured in Diopter) - Crystal Field Splitting Energy Tetrahedral Complexes is the energy of separation between Eg and T2g orbitals.
STEP 1: Convert Input(s) to Base Unit
Crystal Field Splitting Energy Octahedral: 9000 Diopter --> 9000 Diopter No Conversion Required
Crystal Field Splitting Energy Tetrahedral: 0.5 Diopter --> 0.5 Diopter No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
OSSE = CFSEOh-CFSETd --> 9000-0.5
Evaluating ... ...
OSSE = 8999.5
STEP 3: Convert Result to Output's Unit
8999.5 Diopter --> No Conversion Required
FINAL ANSWER
8999.5 Diopter <-- Octahedral Site Stabilization Energy
(Calculation completed in 00.004 seconds)

Credits

Created by Torsha_Paul
University of Calcutta (CU), Kolkata
Torsha_Paul has created this Calculator and 200+ more calculators!
Verified by Soupayan banerjee
National University of Judicial Science (NUJS), Kolkata
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12 Stabilization Energy Calculators

Equilibrium Constant for Coordinate Complexes
Go Formation Constant for Coordinate Complexes = (Concentration of Complex Ion^Stoichiometric Coefficient of Complex Ion)/((Concentration of Metal in Complex^Stoichiometric Coefficient of Metal)*(Concentration of Lewis Bases^Stoichiometric Coefficient of Lewis Base))
Transition Energy from T1g to T1gP
Go Transition Energy from T1g to T1gP = (3/5*Energy Difference)+(15*Racah Parameter)+(2*Configuration Interaction)
Transition Energy from A2g to T1gP
Go Transition Energy from A2g to T1gP = (6/5*Energy Difference)+(15*Racah Parameter)+Configuration Interaction
Octahedral Site Stabilization Energy
Go Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral
Crystal Field Splitting Energy for Tetrahedral Complexes
Go Crystal Field Splitting Energy Tetrahedral = ((Electrons In Eg Orbitals*(-0.6))+(0.4*Electrons In T2g Orbital))*(4/9)
Crystal Field Activation Energy for Dissociative Reaction
Go CFAE Dissociative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Square Pyramidal Intermediate
Crystal Field Splitting Energy for Octahedral Complexes
Go Crystal Field Splitting Energy Octahedral = (Electrons In Eg Orbitals*0.6)+(-0.4*Electrons In T2g Orbital)
Solubility Product of Coordinate Complex
Go Solubility Product of Coordinate Complex = Formation Constant for Coordinate Complexes*Solubility Product
Crystal Field Activation Energy for Associative Reaction
Go CFAE Associative Substitution = Crystal Field Splitting Energy Octahedral-CFSE For Pentagonal Bipyramidal
Transition Energy from A2g to T1gF
Go Transition Energy from A2g to T1gF = (9/5*Energy Difference)-Configuration Interaction
Transition Energy from T1g to T2g
Go Transition Energy from T1g to T2g = (4/5*Energy Difference)+Configuration Interaction
Transition Energy from T1g to A2g
Go Transition Energy from T1g to A2g = (9/5*Energy Difference)+Configuration Interaction

Octahedral Site Stabilization Energy Formula

Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral
OSSE = CFSEOh-CFSETd

What are the application of Octahedral Site Stabilization Energy?

It helps in determining whether the coordination complex will be normal or inverse spinel.In the normal spinel structure, there is a close-packed array of anions. The A-site cations fill 1/8 of the tetrahedral holes and the B-site cations fill 1/2 of the octahedral holes.
Inverse spinels have a closely related structure (with the same large unit cell) in which the A-site ions and half of the B-site ions switch places.

What is a spinel?

The spinel structure is formulated MM'2X4, where M and M' are tetrahedrally and octahedrally coordinated cations, respectively, and X is an anion (typically O or F). The structure is named after the mineral MgAl2O4, and oxide spinels have the general formula AB2O4.

How to Calculate Octahedral Site Stabilization Energy?

Octahedral Site Stabilization Energy calculator uses Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral to calculate the Octahedral Site Stabilization Energy, The Octahedral Site Stabilization Energy formula is defined as the difference between the CFSE values in octahedral and tetrahedral geometries. Octahedral Site Stabilization Energy is denoted by OSSE symbol.

How to calculate Octahedral Site Stabilization Energy using this online calculator? To use this online calculator for Octahedral Site Stabilization Energy, enter Crystal Field Splitting Energy Octahedral (CFSEOh) & Crystal Field Splitting Energy Tetrahedral (CFSETd) and hit the calculate button. Here is how the Octahedral Site Stabilization Energy calculation can be explained with given input values -> 8999.5 = 9000-0.5.

FAQ

What is Octahedral Site Stabilization Energy?
The Octahedral Site Stabilization Energy formula is defined as the difference between the CFSE values in octahedral and tetrahedral geometries and is represented as OSSE = CFSEOh-CFSETd or Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral. Crystal Field Splitting Energy Octahedral is the energy separation between the T2g and Eg orbital & Crystal Field Splitting Energy Tetrahedral Complexes is the energy of separation between Eg and T2g orbitals.
How to calculate Octahedral Site Stabilization Energy?
The Octahedral Site Stabilization Energy formula is defined as the difference between the CFSE values in octahedral and tetrahedral geometries is calculated using Octahedral Site Stabilization Energy = Crystal Field Splitting Energy Octahedral-Crystal Field Splitting Energy Tetrahedral. To calculate Octahedral Site Stabilization Energy, you need Crystal Field Splitting Energy Octahedral (CFSEOh) & Crystal Field Splitting Energy Tetrahedral (CFSETd). With our tool, you need to enter the respective value for Crystal Field Splitting Energy Octahedral & Crystal Field Splitting Energy Tetrahedral and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
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